OSA Optical analysis of a solar thermochemical system
We propose a concept of a rotating tower reflector (TR) in a beam-down optical system to alternate concentrated solar irradiation of an array of solar receiver–reactors realizing multi-step solar thermochemical redox cycles. Optical and radiative characteristics of the proposed system are explored analytically and numerically by Monte-Carlo ray-tracing simulations.
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Estimation of solar‐to‐fuel energy conversion efficiency
Apr 21 2020 · Estimation of the solar‐to‐fuel energy conversion efficiency (with and without heat recuperation) of the Sm 2 O 3 /SmO‐based solar‐driven thermochemical CO 2 splitting cycle is reported. HSC Chemistry 9.9 software and its thermodynamic database were utilized for the thermodynamic analysis.
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Solar Hydrogen Production via a Samarium Oxide-Based
The computational thermodynamic analysis of a samarium oxide-based two-step solar thermochemical water splitting cycle is reported. The analysis is performed using HSC chemistry software and databases. The first (solar-based) step drives the thermal reduction of Sm2O3 into Sm and O2. The second (non-solar) step corresponds to the production of H2 via a water splitting reaction and the
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Integration of thermochemical water splitting with CO2
Dec 10 2019 · Global warming as a result of rising atmospheric CO2 concentrations is considered an imminent threat to society. In order to address rising CO2 concentrations effective CO2 capture directly from the atmosphere is likely to be necessary. We integrate direct air capture CO2 and water splitting to produce a mixture of CO2 and H2 via a thermochemical water-splitting cycle.
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Concentration-Dependent Solar Thermochemical CO2/H2O
splitting (CDS) and water splitting (WS) reactions after methane partial oxidation (MPO) are investigated for syngas yield and purity. This study advances the field of solar thermochemistry towards achieving efficient and low-cost oxygen carriers for enhanced solar fuel produc-tion via thermochemical redox cycles. 2. Materials and Methods 2.1.
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Solar thermochemical reactor technology for splitting CO2
ABSTRACT The solar-driven thermochemical splitting of CO 2 into separate streams of CO and O 2 is experimentally demonstrated with total selectivity long-term stability high mass conversion and promising solar-to-fuel energy efficiency.
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Solar thermochemical reactor technology for splitting CO2
ABSTRACT The solar-driven thermochemical splitting of CO 2 into separate streams of CO and O 2 is experimentally demonstrated with total selectivity long-term stability high mass conversion and promising solar-to-fuel energy efficiency.
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CICECO » Solar thermochemical production of hydrogen based
A Review of Solar Thermochemical CO2 Splitting Using Ceria-Based Ceramics With Designed Morphologies and Microstructures 2019 FRONTIERS IN CHEMISTRY 7 A sustainable multi-function biomorphic material for pollution remediation or UV absorption Aerosol assisted preparation of highly porous ZnO-based materials from cork templates
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Perovskite nanocomposites as effective CO2-splitting
The peak CO production rate in this open-loop thermochemical scheme was one order of magnitude higher than that in conventional solar-thermal CO 2 splitting which was carried out at temperatures
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Frontiers Dual Hydrogen- and Oxygen-Transport Membrane
The solar thermochemical approach to dissociate CO 2 and H 2 O is promising because it utilizes the entire solar spectrum in the form of high-temperature process heat and thus enables thermodynamically favorable reactions and the potential of reaching high energy
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Solar‐thermal production of renewable hydrogenPerkins
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Numerical Modeling of CO2 Splitting in High-Temperature
Aug 24 2020 · H 2 /CO production via H 2 O/CO 2 splitting powered by concentrated solar energy is a promising pathway for energy conversion/storage. Oxygen permeable membrane reactor serves as an alternative reactor concept for realizing this chemical path with the advantages of continuous production easy integration and high product selectivity.
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Review of the Two-Step H2O/CO2-Splitting Solar
Review of the Two-Step H2O/CO2-Splitting Solar Thermochemical Cycle Based on Zn/ZnO Redox Reactions
Get PriceReview of the Two-Step H2O/CO2-Splitting Solar
This article provides a comprehensive overview of the work to date on the two‑step solar H2O and/or CO2 splitting thermochemical cycles with Zn/ZnO redox reactions to produce H2 and/or CO i.e. synthesis gas—the precursor to renewable liquid hydrocarbon fuels. The two-step cycle encompasses (1) The endothermic dissociation of ZnO to Zn and O2 using concentrated solar energy as the source
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Concentration-Dependent Solar Thermochemical CO2/H2O
splitting (CDS) and water splitting (WS) reactions after methane partial oxidation (MPO) are investigated for syngas yield and purity. This study advances the field of solar thermochemistry towards achieving efficient and low-cost oxygen carriers for enhanced solar fuel produc-tion via thermochemical redox cycles. 2. Materials and Methods 2.1.
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Factors Affecting the Efficiency of Solar Driven Metal
A Review of Solar Thermochemical CO2 Splitting Using Ceria-Based Ceramics With Designed Morphologies and Microstructures. Frontiers in Chemistry 2019 7 https //doi/10.3389/fchem.2019.00601 Hui Kong Xianghui Kong Hongsheng Wang Jian Wang.
Get PriceOSA Optical analysis of a solar thermochemical system
We propose a concept of a rotating tower reflector (TR) in a beam-down optical system to alternate concentrated solar irradiation of an array of solar receiver–reactors realizing multi-step solar thermochemical redox cycles. Optical and radiative characteristics of the proposed system are explored analytically and numerically by Monte-Carlo ray-tracing simulations.
Get PriceSolar Splitting of H2O and CO2 via Thermochemical Redox
The thermochemical oxygen production is experimentally demonstrated by applying a temperature/pressure swing between 573 K at 0.2 bar O2 and 873 K at 1 bar O2. An energy balance shows the feasibility of using process waste heat from the solar thermochemical CO2/H2O splitting cycle and the potential to compete vis-a-vis with cryogenic distillation.
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Thermochemical CO2 and CO2/H2O Splitting over NiFe2O4
Selection and peer review by the scientifi c conference committee of SolarPACES 2013 under responsibility of PSE AG. Final manuscript published as received without editorial corrections. doi 10.1016/j.egypro.2014.03.212 SolarPACES 2013 Thermochemical CO 2 and CO 2/H 2O splitting over NiFe 2O 4 for solar fuels synthesis
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A review of high temperature solar driven reactor
As representative examples and spanning over 25years of solar reactor research and development by the Solar Technology Laboratory at the Paul Scherrer Institute five projects have been selected and are presented in detail H2O and CO2 splitting via the Zn/ZnO thermochemical cycle brought to the 100kW level carbothermal reduction of ZnO
Get PriceSolar Splitting of H2O and CO2 via Thermochemical Redox
The thermochemical oxygen production is experimentally demonstrated by applying a temperature/pressure swing between 573 K at 0.2 bar O2 and 873 K at 1 bar O2. An energy balance shows the feasibility of using process waste heat from the solar thermochemical CO2/H2O splitting cycle and the potential to compete vis-a-vis with cryogenic distillation.
Get PriceSolar photochemical and thermochemical splitting of water
Another strategy to convert solar energy to chemical energy is by thermochemical splitting of H 2 O into H 2 a strategy that can also be used to reduce CO 2 to CO. Thermochemical processes performed using solar concentrators can achieve high solar-to-fuel conversion efficiencies as they allow the utilization of the entire solar spectrum besides the thermal energy.
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(PDF) A Review of Solar Thermochemical CO2 Splitting Using
A Review of Solar Thermochemical CO2 Splitting Using Ceria-Based Ceramics With Designed Morphologies and Microstructures. Frontiers in Chemistry 2019. Robert C Pullar. Rui Novais. Stéphane Abanades. Robert C Pullar. Rui Novais. Stéphane Abanades. Download PDF. Download Full PDF Package. This paper.
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Review of the Two-Step H2O/CO2-Splitting Solar
Review of the Two-Step H2O/CO2-Splitting Solar Thermochemical Cycle Based on Zn/ZnO Redox Reactions
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(PDF) A Review of Solar Thermochemical CO2 Splitting Using
This review explores the advances in the synthesis of ceria materials with specific morphologies or porous macro- and microstructures for the solar-driven production of carbon monoxide (CO) from
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Thermodynamic assessment of hydrogen production via solar
Solar thermochemical conversion of CO2 into fuel via two-step redox cycling of non-stoichiometric Mn-containing perovskite oxides. Journal of Physical Chemistry A 2015 3(7) 3536–3546 13 J R Scheffe D Weibel A Steinfeld. Lanthanum-strontium-manganese perovskites as redox materials for solar thermochemical splitting of H2O and CO2.
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Concentration-Dependent Solar Thermochemical CO2/H2O
The effects of V and Ce concentrations (each varying in the 0–100 range) in vanadia–ceria multiphase systems are investigated for synthesis gas production via thermochemical redox cycles of CO 2 and H 2 O splitting coupled to methane partial oxidation reactions. The oxidation of prepared oxygen carriers is performed by separate and sequential CO2 and H2O splitting
Get PriceSplitting CO2 with a ceria‐based redox cycle in a solar
Using concentrated solar energy thermochemical redox cycles based on nonstoichiometric metal oxides are capable of splitting H 2 O and CO 2 to produce H 2 and CO (syngas) the precursor for the synthesis of conventional transportation liquid fuels. 1 Due to its favorable oxidation thermodynamics rapid reaction kinetics and morphological
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Loop Jean-Michel Lavoie
After a B.Sc in chemistry Dr. JM Lavoie followed his academic training with a MSc and a Ph.D in wood science and technology at Université Laval (Québec) under the supervision of Pr. Tatjana Stevanovic (). From 2005 to 2007 he worked as an Assistant Professor in the Chemistry and Biochemistry Department at Université de Moncton (New-Brunswick). In 2007 he decided to go back to
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